Life

Why heat is not a function of state?

Why heat is not a function of state?

A state function is independent of pathways taken to get to a specific value, such as energy, temperature, enthalpy, and entropy. Enthalpy is the amount of heat released or absorbed at a constant pressure. Heat is not a state function because it is only to transfer energy in or out of a system; it depends on pathways.

Why work done is state function?

As, we know the property or a function which does not depend on the path is called a state function. Work-done in adiabatic processes is equal to the negative of change in internal energy from the first law of thermodynamics. So, it is a state function. This is path independent, hence it is a state function.

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Why entropy is a state function but heat is not?

Entropy is surely a state function which only depends on your start and end states, and the change in entropy between two states is defined by integrating infinitesimal change in entropy along a reversible path. But heat Q is not a state variable, the amount of heat gained or lost is path-dependent.

Why temperature is a state function?

Temperature is a state function as it is one of the values used to define the state of an object. Furthermore, temperature is dependent on the final and initial values, not on the path taken to establish the values.

Is not a state function?

Work is not a state function as during a process its value depends on the path followed. The value of enthalpy, internal energy entropy depends on the state and not on the path followed to get that state, hence these are state functions.

Why are heat and work path functions?

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As an example, mechanical work and heat are process functions because they describe quantitatively the transition between equilibrium states of a thermodynamic system. Path functions depend on the path taken to reach one state from another. Different routes give different quantities.

When entropy is a state function?

Entropy is a State Function because it depends only on the initial and final thermodynamic states and not on the path followed.

Is total entropy a state function?

Since entropy is a state function, the entropy change of the system for an irreversible path is the same as for a reversible path between the same two states.

Why work and heat are path functions?

Heat and work are path functions because they depend on the actual path traversed to move from initial to final state of the system.

Which following is not a state function?

Work is not a state function as it depends upon the path followed.

Why is Q not a state function?

q isn’t a state function because it isn’t solely dependent on the initial and final states; the value of q depends on the pathway taken to reach the final q. Here is an example of why heat is not a state property: Consider raising the temperature of 50.0g of water from 25.0°C to 50.0°C.