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Why is KCl a salt bridge instead of NaCl?

Why is KCl a salt bridge instead of NaCl?

For a salt to be used in salt bridge, the mobility of cationic and anions part should be same. This property is possessed by KCl because of similar sizes of K+ and Cl- ions. In NaCl, the sizes of Na+ and Cl- are quite different that’s why it is not used in salt bridges.

Why only KCl and nh4no3 are used in salt bridge?

Answer: KCl and KNO3 are used to maintain the neutrality of the cells. The salt bridge provides cations and anions to replace the ions lost or produced in the two half cells. Therefore, it do not disturb the neutrality of the cell but infact helps to maintain it. …

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Why KCl is used as electrolyte?

The electrolyte in the salt bridge is chosen so that it does not react with any of the chemicals used in the cell. The anion and cation have similar conductivity, and hence similar migratory speed. Potassium ion and Chlorine ion also have the same ionic mobilities.

Which salt is used in salt bridge?

In empirical settings, the salt bridge is often an inverted glass U-shaped tube filled with sodium chloride. Its two legs dip into two separate vessels of electrolyte (the half-cells) to form an electrochemical cell.

Why KCl is used in pH meter?

Potassium chloride (KCl) acts as a source of chloride ions for the electrode. The advantage of using KCl for this purpose is that it is pH-neutral. Typically, KCl solutions of concentrations ranging from 3 molar to saturated are used in pH meters.

Which chemical is used in salt bridge?

It is usually a combination of potassium or ammonium ions and chloride or nitrate ions, which have similar mobility in solution. The combination is chosen which does not react with any of the chemicals used in the cell.

What can be used as a salt bridge?

Many things can be used as a salt bridge: a piece of string, cotton, or filter paper soaked in an electrolyte solution or an electrolyte solution in a gel such as agar. Occasionally, fritted glass (porous glass), though not a salt bridge, is used to connect two half-cells.

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Which electrolyte is used in the salt bridge?

One type of salt bridge consists of a U-shaped glass tube filled with a relatively inert electrolyte. It is usually a combination of potassium or ammonium ions and chloride or nitrate ions, which have similar mobility in solution.

Is KCl acidic or basic?

The ions from KCl derive from a strong acid (HCl) and a strong base (KOH). Therefore, neither ion will affect the acidity of the solution, so KCl is a neutral salt.

Is cathode a reduction?

The cathode is where reduction takes place and oxidation takes place at the anode. Through electrochemistry, these reactions are reacting upon metal surfaces, or electrodes. An oxidation-reduction equilibrium is established between the metal and the substances in solution.

Why is KCl used in salt bridge instead of NaCl?

With this principal KCL is used to maintain neutrality in the solution containing solution so reaction is not reached equlibrium as faster. This property is possessed by KCl because of similar sizes of K+ and Cl- ions. In NaCl, the sizes of Na+ and Cl- are quite different that’s why it is not used in salt bridges.

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What is the purpose of using KCL in saltrbridge?

KCl used to make the solution neutral without mixing in the solution. Charges (ions) (+ or – Q) flow due to presence of ELECTRIC FIELD (E).In saltrbridge our U bridge ELECTRIC FIELD is existed due to electric fied of ions and electrodes.

What is a salt bridge in chemistry?

A salt bridge is a U-shaped tube containing concentrated solution of an inert electrolyte like KCl, KNO3, K2SO4 etc. The function of the salt bridge is to allow the movement of ions from one solution to other without mixing of the two solutions.

Why KNO3 is used in salt bridge?

Similarly, why kno3 is used in salt bridge? The main function of salt bridge is to maintain neutrality of the system. So, it provides negative ions to excess positive charge and positive ions to excess negative charge,hence,keeping the system neutralised. For this reason KCL / KNO3 are used in a salt bridge.