What is linkage isomers give an example?

Linkage isomerism → Linkage isomerism is the existence of coordination compounds that have the same composition differing with the connectivity of the metal to a ligand. E.g.- Thiocyanate (CN−) and isothiocyanate (SCN−) ion are linkage isomers.

What is linkage isomerism?

Linkage isomers are two or more coordination compounds in which the donor atom of at least one of the ligands is different (i.e., the connectivity between atoms is different). This type of isomerism can only exist when the compound contains a ligand that can bond to the metal atom in two (or more) different ways.

What is linkage isomers explain with an example shaala?

Linkage isomerism arises when an ambidentate ligand is bonded to the central metal atom/ion through either of its two different donor atoms. e.g. – [Co(NH3)5NO2]2+ Pentaammine nitrito-κN Cobalt (III) ion – N attached.

Which will show linkage isomerism?

Ambidentate ligands can show linkage isomerism.

Which among the following can linkage isomer?

[Cr(H2O)5SCN]3+ can form linkage isomer, as here more than one atom of a monodentate ligand may function as a donor.

Can you exhibit linkage isomerism?

-NO2 is ambidentate ligand as it connect with metal by N or O atom.

Which of the ligands can show linkage isomerism?

Ambidentate ligands can show linkage isomerism .

Which of the following is linkage isomers?

Coordination compounds containing a ligand with more than one non-equivalent binding position (known as ambident ligand) show linkage isomerism. Hence, [Co(NH3)5(NO2)]2+ and [Cr(NH3)5SCN]2+ show linkage isomerism.

Which of the following can form linkage isomers?

NO−2 can participate in linkage isomerism because it may be bonded to metal through nitrogen or through oxygen.

Which among the following can form linkage isomerism?

[Pt(NH3​)2​Cl2​]

Which one of the following is an example of linkage isomerism select one?

Examples of linkage isomers are violet-colored [(NH3)5Co-SCN]2+ and orange-colored [(NH3)5Co-NCS]2+. The isomerization of the S-bonded isomer to the N-bonded isomer occurs intramolecularly.