Advice

Is exothermic spontaneous at low temperatures?

Is exothermic spontaneous at low temperatures?

An exothermic process, non-spontaneous at high temperature, will become spontaneous at low temperature.

Why is a reaction spontaneous at low temperatures?

If ΔH and ΔS are both negative, the reaction is only spontaneous at low temperatures. This is because at low temperatures the entropy term will be a smaller positive number, making it more likely that the negative enthalpy can drive the spontaneity of the reaction.

Why are endothermic reaction spontaneous at higher temperatures?

An endothermic reaction can be spontaneous if entropy increases by more than the change in enthalpy. For endothermic r̥eactions, ΔH> 0 and thus if the value of −TΔS overshadows the ΔH value (usually at very high temperatures) then the overall value of ΔG becomes negative and thus the reaction becomes spontaneous.

READ ALSO:   What is the behavior of the Sun during winter?

Would you expect the reaction to be spontaneous at higher or lower temperatures?

If ΔH is negative, and –TΔS positive, the reaction will be spontaneous at low temperatures (decreasing the magnitude of the entropy term). If ΔH is positive, and –TΔS negative, the reaction will be spontaneous at high temperatures (increasing the magnitude of the entropy term).

Are all exothermic processes spontaneous explain?

Are all exothermic reactions spontaneous? No, but all reactions that are spontaneous at standard state (interpreted to mean that at standard state, equilibrium lies in the forward direction, i.e. K > 1 and ΔrG∘<0) are either exothermic (ΔrH∘<0) or show a positive standard entropy of reaction (ΔrS∘>0), or both.

Which of the following reaction is spontaneous at low temperature?

At a relatively low temperature (below 273K), the melting is not spontaneous because the positive ΔH term “outweighs” the TΔS term….Gibbs Free Energy.

ΔH ΔS ΔG
negative positive always negative
positive positive negative at higher temperatures, positive at lower temperatures
READ ALSO:   How can I learn two languages in LaTeX?

Is an endothermic reaction more likely to be spontaneous at higher temperatures or lower temperatures explain?

For an endothermic reaction, For a reaction to be spontaneous, Hence, Which happens at higher temperature. Thus, at higher temperature, endothermic reaction is more likely to be spontaneous.

How can you relate exothermic and endothermic processes on spontaneous process?

Chemical reactions are spontaneous when they proceed on their own; you may have to initiate them with a spark or other source of energy, but once triggered, they go to completion without further input. Most spontaneous reactions are also exothermic — they produce heat or other forms of energy, as fire does.

What does it mean when a reaction is spontaneous?

In chemistry, a spontaneous processes is one that occurs without the addition of external energy. A spontaneous process may take place quickly or slowly, because spontaneity is not related to kinetics or reaction rate.

Are all spontaneous reactions exothermic?

All spontaneous processes are not exothermic, because it is the Gibbs Free energy that determines spontaneity, not the enthalpy. You will notice that this expression may be positive even with a negative enthalpy change (exothermic process) if the entropy change is negative and the temperature is high enough.